Just painted my 944 Turbo calipers which are also Brembo. Lacquer is peeling from my 996 calipers so will be trying to look at doing this on them in the Winter.
I stripped the old paint using some proper bodyshop paint stripper (you can find tins of this on ebay). Looks like wallpaper paste but make sure you wear plenty of PPE when using it in a well ventilated environment.
The calipers already had a rough finish so I didn't need to sand them, but as others have said worth doing this just to provide a key for the paint to stick to.
The old style calipers from the 944 were anodised black by Porsche and the simply clear coated (not painted). Not sure if that is the same process for the 996 calipers or not as haven't stripped mine yet.
I used VHT Brake Caliper Paint, Gloss Black and Clear Coat.
I baked them at 75C for a couple of hours in my food dehydrator and then fitted new seals which I got from Bigg Red. I also ended up having to get one 28mm piston as one of the bores had a tiny bit of aluminium corrosion on the lip which had damaged the piston.
I repaired some pitting in the aluminium under the slide plates with some JB Weld (don't knock it till you've tried it).
Preparation is key to all of this, I think I must have washed the calipers about 5 times before painting. Shout out to Adam at Uber9 where I got the stickers from, the only place I could find selling the correct font style for the older style Brembo brakes. Most seem to sell the more modern 996 / Boxster font which is thinner.
I used VHT Gloss Black caliper paint, left it to dry for 7 days and then applied the decals, followed by some VHT Gloss Clear caliper paint.